Place chops on the unheated rack of a broiler pan. Broil 3 to 4 inches from heat for 10 to 15 minutes or until medium doneness (160 degrees F), turning once halfway through broiling time. Transfer to a serving platter.
Meanwhile, coat an unheated large nonstick skillet with nonstick cooking spray. Preheat over medium heat. Add sweet peppers, oregano, and garlic to hot skillet. Cook and stir for 6 to 8 minutes or until sweet peppers are crisp-tender. Stir in olives; heat through. Spoon sweet pepper mixture over chops. If desired, garnish with whole chile peppers. Makes 4 servings.